A collaborative ultrafast spectroscopy and ab initio molecular dynamics simulations study shows that proton vacancies in the form of hydroxide/methoxide ions are as relevant for proton transfer between acids and bases as hydrated excess protons, thus pointing for a clear demand for refinement of the microscopic picture for aqueous proton transport - in solution as well as in hydrogen fuel cells or transmembrane proteins - away from currently often assumed dominant role of hydrated excess protons.
from Latest Science News -- ScienceDaily https://ift.tt/2AVPByq
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